热扩散驱动的元素分异和同位素分馏:一种不容忽视的硅酸盐成分分异机制     

常翱飞  丁兴 《岩石学报》2020,36(1):99-112

热扩散在地质过程中是否发挥重要作用一直存有争议。本文回顾了热扩散的研究历史和现状,重点总结了热扩散驱动的元素和同位素行为规律,并探讨了温度、硅酸盐组分、压力和氧逸度等因素对热扩散行为的影响。已有的研究表明,稳定热梯度下的硅酸盐热扩散效应类似于结晶分异或AFC过程,可以造成轻、重同位素分别在高温端和低温端富集,而主、微量元素的扩散方向则取决于两端化学势的高低和熔体中的电价平衡。从基性岩浆到酸性岩浆,熔体聚合度增大,黏度增加,热扩散速率明显降低,成网元素的热扩散效应减弱,变网元素则反之;水、氟、氯和硫化氢等挥发组分能增加熔体的非桥氧比例,降低熔体聚合度,因而能显著增强硅酸盐熔体中元素和同位素的热扩散效应。在此基础上,本文提出了当前硅酸盐体系热扩散研究中存在的五个亟需解决的问题,即:1)对不同硅酸盐体系的热扩散规律的研究还不够全面;2)对微量元素的热扩散行为认识不足;3)硅酸盐体系热扩散作用的影响因素及尺度还不够明确;4)热扩散作用的地质与地球化学关键识别标志有待确立;5)硅酸盐体系热扩散作用的理论模型有待建立。尽管硅酸盐体系热扩散的研究还存在诸多不足,但越来越多的证据表明,热扩散是地质过程中不容忽视的一种成分分异机制。这种机制会造成岩浆房或岩浆通道中的元素分异和同位素分馏,可能对于一些成分分异的岩石和矿床的形成具有重要的意义。  相似文献   

Interpreting zirconium‐in‐rutile thermometric results          下载免费PDF全文

K. Taylor‐Jones  R. Powell 《Journal of Metamorphic Geology》2015,33(2):115-122

At first sight, experimental results and observations on rocks suggest that the Zr content in rutile, where equilibrated with quartz and zircon, should be a useful thermometer for metamorphic rocks. However, diffusion data for Zr in rutile imply that thermometry should not, for plausible rates of cooling, give the high temperatures commonly observed in high‐grade metamorphic rocks. It is suggested here that such observations can be accounted for by high‐T diffusive closure of Si in rutile, causing the interior of rutile grains to become insensitive to the thermometer equilibrium well above the temperature of Zr diffusive closure. Paired with comparatively slow grain boundary diffusion and problematic zircon nucleation, this allows for cases of Zr retention in rutile through temperatures where Zr is still diffusively mobile within rutile grains. Other observations that may be accounted for in this context are large inter‐grain ranges of rutile Zr contents uncorrelated with rutile grain size, and flat Zr profiles across individual rutile grains, counter to what would be expected from diffusive closure. A consequence is that it is unlikely that Zr‐in‐rutile thermometry will be useful for estimating rock cooling rates.  相似文献   

Intergranular diffusion rates from the analysis of garnet surfaces: Implications for metamorphic equilibration          下载免费PDF全文

Tim J. Dempster  Shona Symon  Peter Chung 《Journal of Metamorphic Geology》2017,35(6):585-600

Novel approaches to garnet analysis have been used to assess rates of intergranular diffusion between different matrix phases and garnet porphyroblasts in a regionally metamorphosed staurolite‐mica‐schist from the Barrovian‐type area in Scotland. X‐ray maps and chemical traverses of planar porphyroblast surfaces reveal chemical heterogeneity of the garnet grain boundary linked to the nature of the adjacent matrix phase. The garnet preserves evidence of low temperature retrograde exchange with matrix minerals and diffusion profiles documenting cation movement along the garnet boundaries. Garnet–quartz and garnet–plagioclase boundaries preserve evidence of sluggish Mg, Mn and Fe diffusion at comparable rates to volume diffusion in garnet, whereas diffusion along garnet–biotite interfaces is much more effective. Evidence of particularly slow Al transport, probably coupled to Fe³⁺ exchange, is locally preserved on garnet surfaces adjacent to Fe‐oxide phases. The Ca distribution on the garnet surface shows the most complex behaviour, with long‐wavelength heterogeneities apparently unrelated to the matrix grain boundaries. This implies that the Ca content of garnet is controlled by local availability and is thought likely to reflect disequilibrium established during garnet growth. Geochemical anomalies on the garnet surfaces are also linked to the location of triple junctions between the porphyroblasts and the matrix phases, and imply enhanced transport along these channels. The slow rates of intergranular diffusion and the characteristics of different boundary types may explain many features associated with the prograde growth of garnet porphyroblasts. Thus, minerals such as quartz, Fe‐oxides and plagioclase whose boundaries with garnet are characterized by slow intergranular diffusion rates appear to be preferentially trapped as inclusions within porphyroblasts. As such grain boundary diffusion rates may be a significant kinetic impediment to metamorphic equilibrium and garnet may struggle to maintain chemical and textural equilibrium during growth in pelites.  相似文献   

黑龙江省暴雪时空分布特征与发生风险研究   总被引：2，自引：1，他引：1  

张丽娟  陈红  刘栋  张利  周东颖 《冰川冻土》2011,33(4):721-728

暴雪是黑龙江省常见的灾害性天气之一,基于1970～2006年黑龙江省78个市（县）的逐日降雪资料,对暴雪初、终日分布规律,暴雪的时间、空间分布特征进行分析,采用信息扩散理论计算了各市（县）发生不同暴雪日数的概率风险估计值,并结合GIS技术进行风险区划．研究表明：黑龙江省暴雪初始日期和终止日期37a来变化不大,初始日出现...  相似文献   

Noble Gas Diffusion Mechanism in Lunar Soil Simulant Grains:Results from ~4He~+ Implantation and Extraction Experiments     

付晓辉  邹永廖  郑永春  贺怀宇  欧阳自远 《中国地质大学学报(英文版)》2011,(5)

Experiments on ion implantation were performed in order to better characterize diffusion of noble gases in lunar soil.4He+ at 50 keV with 5×1016 ions/cm2 was implanted into lunar simulants and crystal ilmenite.Helium in the samples was released by stepwise heating experiments.Based on the data,we calculated the helium diffusion coefficient and activation energy.Lunar simulants display similar 4He release patterns in curve shape as lunar soil,but release temperatures are a little lower.This is probably a con...  相似文献   

台湾海峡西部沉积物中碳的来源及埋藏   总被引：4，自引：1，他引：3  

叶翔  陈坚  王爱军  黄财宾  汪卫国  李东义 《海洋学报》2011,33(5):73-82

根据2005年夏季航次观测的沉积物中总有机碳(TOC)、无机碳(CaCO3)、总氮(TN)、悬浮体颗粒有机碳(POC)、沉积物粒度数据得出,台湾海峡西部表层沉积物TOC质量分数的范围为0.01～1.79,平均值为0.37±0.24,略高于20多年前台湾海峡南部海区,而低于台湾海峡中、北部海区;TOC的质量分数湾内比湾外...  相似文献   

基于扩散滤波的多尺度三维变分研究   总被引：4，自引：0，他引：4  

李冬  王喜冬  张学峰  吴新荣  李威  韩桂军 《海洋通报》2011,30(2):165-171

将扩散方程引入三维变分分析,揭示了传统3D-VAR不能有效提取多尺度观测信息的根本原因,即观测导致的目标函数梯度在空间的不连续分布.将扩散滤波融入基于梯度的最优化算法,发展了基于扩散滤波的多尺度3D-VAR.海表面温度数据同化试验结果表明,新方法可从长波至短波有效地提取多尺度的观测信息.  相似文献   

深海环境中溢油输移扩散的初步数值模拟     

廖国祥  杨建强  高振会 《海洋通报》2011,30(6):707-712

通过对溢油在深海环境中的输移过程及行为特点的分析,初步建立基于拉格朗日积分法的深海溢油模型.该模型除了能够模拟油气混合物在真实深海环境中的共同输移与分离输移扩散过程,还考虑了石油溶解、气体溶解、天然气水合物形成与分解等行为变化对溢油运动轨迹的影响.应用该模型初步数值模拟了一次实际深海溢油试验,结果表明溢油在水下的空间分...  相似文献   

围海造陆工程泄水口悬浮物扩散规律分析   总被引：1，自引：1，他引：0  

陈杰  蒋昌波  张绍华  胡保安 《海洋科学》2015,39(8):58-62

掌握围海造陆工程泄水口悬浮物扩散规律,对保护海洋水环境质量具有重要意义。选取围海造陆工程泄水口为研究对象,基于泥沙对流扩散方程,推求出泄水口悬浮物扩散平面二维分析解表达式。开展现场观测,确定泄水口源强取值,并对泄水口悬浮物扩散进行理论计算和分析。研究结果显示,围海造陆工程施工后期,泄水口悬浮物流失非常严重。泄水口附近水域出现的最大悬浮物浓度主要由源强的大小来决定,悬浮物扩散范围主要由流速的大小来控制。  相似文献   

黄河沉积物向渤海湾扩散的沉积地球化学示踪   总被引：1，自引：0，他引：1       下载免费PDF全文

张爱滨  刘明  廖永杰  张艳丽  范德江 《海洋科学进展》2015,33(2):246-256

使用ICP-AES和ICP-MS对渤海中部118°54′E左右南北向断面的表层沉积物中53种常、微量及稀土元素进行了测试,研究了其含量变化和分布特征,并进行了物质组成分析。研究表明:该区沉积物以B94站为界,南北差异明显,南部区域沉积物以黏土质粉砂为主,富集Al2O3,CaO,Fe2O3,MgO,MnO,P2O5和TiO等常量元素以及绝大多数的微量元素和稀土元素等与细颗粒黏土矿物相关的元素;北部区域沉积物以粉砂-砂为主,富集SiO2,K2O和Na2O等常量元素以及Zr,Ba,Sr,Sb和Hf等微量元素,稀土元素相对亏损。物源对比表明南部沉积物具有黄河来源沉积物特点,北部沉积物具有滦河来源特点,两者的分界大致在38°42′N附近。河口动力过程、渤海环流是影响该区沉积物扩散的主要因素。  相似文献